Diaquabis(4,4′-bipyridine-κ N )bis(2,4,5-trifluoro-3-hydroxybenzoato-κ O 1 )manganese(II)

Diaquabis(4,4′-bipyridine-κ N )bis(2,4,5-trifluoro-3-hydroxybenzoato-κ O 1 )manganese(II)

In the title compound, [Mn(C7H2F3O3)2(C10H8N2)2(H2O)2], the MnII ion, situated on a centre of inversion, has a distorted octahedral coordination geometry and is coordinated by two N atoms from two 4,4′-bipyridine ligands, two O atoms from two 2,4,5-trifluoro-3-hydroxybenzoate ligands and t...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Vol. 67; no. 12; p. m1826
Main Authors: Min, Chun-Gang, Yang, Xi-Kun
Format: Journal Article
Language:English
Published: International Union of Crystallography 01-12-2011
Online Access:Get full text
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Summary:In the title compound, [Mn(C7H2F3O3)2(C10H8N2)2(H2O)2], the MnII ion, situated on a centre of inversion, has a distorted octahedral coordination geometry and is coordinated by two N atoms from two 4,4′-bipyridine ligands, two O atoms from two 2,4,5-trifluoro-3-hydroxybenzoate ligands and two water molecules. Intermolecular O—H...N hydrogen bonds link the molecules into a chain along the a axis. Interactions between neighboring chains occur through O—H...O hydrogen bonds, which link the chains into a two-dimensional supramolecular network parallel to the ac plane. In addition, O—H...O hydrogen bonds between the water molecules and carboxylate groups also exist in the the crystal structure.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536811049610