Conductivity of graphene oxide films: Dependence from solvents and photoreduction

• Published in: Chemical physics letters Vol. 583; pp. 155 - 159
• Main Authors: Smirnov, V.A., Denisov, N.N., Ukshe, A.E., Shulga, Yu.M.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 17-09-2013
• ISSN: 0009-2614; 1873-4448
• DOI: 10.1016/j.cplett.2013.08.019

[Display omitted]
•Conductivity of graphene oxide (GO) films of 200–500nm thickness.•Isotopic effect for the conductivity being σH/σD=1.4±0.1.•Proton character conductivity is concluded.•The conductivity increases in vapors of polar solvents.•The UV reduction of GO reduces the film sensitivity toward moisture.
The moisture effect on conductivity of graphene oxide (GO) films was studied. GO films of 200–500nm thickness become conductive (Ω ranges from 10−6 to 10−2S/cm) upon the moisture increase from 30% to 100%. Waters diffusion changes the films morphology. The UV reduction of GO reduces the film sensitivity toward moisture until the complete disappearance. Proton character conductivity is concluded for GO, the isotopic effect for the conductivity being σH/σD=1.4±0.1. The GO film conductivity increases in polar solvents vapors (alcohols, acetone, pyridine, etc.), however, nonpolar (toluene and hexane) and chlorine containing (СCl4, CHCl3) solvents vapors do not affect the conductivity.