Reaction of unsymmetrical trifluoromethyl-containing 1,3-dicarbonyl compounds with ‘push–pull’ enamines

The reaction of ‘push–pull’ enamines with trifluoromethyl-containing 1,3-dicarbonyl compounds was investigated. It was found that the reaction is sensitive both to the structure of the enamines and to reaction conditions. As a result, a set of various trifluoromethyldialkylanilines was obtained....

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Bibliographic Details
Published in:	Tetrahedron letters Vol. 48; no. 15; pp. 2775 - 2779
Main Authors:	Sibgatulin, Dmitriy A., Volochnyuk, Dmitriy M., Kostyuk, Alexander N.
Format:	Journal Article
Language:	English
Published:	Elsevier Ltd 09-04-2007
Subjects:	4,4,4-Trifluoroacetoacetate Cyclocondensation Trifluoromethylated benzenes ‘Push–pull’ enamines ‘Push–pull’ enamines 4,4,4-Trifluoroacetoacetate Cyclocondensation Trifluoromethylated benzenes
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Summary:	The reaction of ‘push–pull’ enamines with trifluoromethyl-containing 1,3-dicarbonyl compounds was investigated. It was found that the reaction is sensitive both to the structure of the enamines and to reaction conditions. As a result, a set of various trifluoromethyldialkylanilines was obtained.
ISSN:	0040-4039 1873-3581
DOI:	10.1016/j.tetlet.2007.02.044