A novel porous coordination polymer based on rigid and flexible organic ligands

A novel porous coordination polymer based on rigid and flexible organic ligands

A novel porous bilayered coordination polymer has been successfully synthesized, and its structures were determined by single-crystal X-ray diffraction studies. By topological approach, the whole structure is a unprecedented 3,4,4-connected network with a Schäfli symbol of (63)2(64·82)2(65·10). PXRD...

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Bibliographic Details
Published in:Inorganic chemistry communications Vol. 13; no. 4; pp. 514 - 517
Main Authors: Xing, Yan-yan, Lin, Jian-guo, Xu, Yan-yan, Duan, Xian-ying, Li, Yi-zhi, Wang, Fang-ming, Meng, Qing-jin
Format: Journal Article
Language:English
Published: Elsevier B.V 01-04-2010
Subjects:
Adsorption
Permanent porosity
Porous coordination polymer
Topology
Topology
Adsorption
Porous coordination polymer
Permanent porosity
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Summary:A novel porous bilayered coordination polymer has been successfully synthesized, and its structures were determined by single-crystal X-ray diffraction studies. By topological approach, the whole structure is a unprecedented 3,4,4-connected network with a Schäfli symbol of (63)2(64·82)2(65·10). PXRD and TGA indicate it is a rare example of a MOF with the framework being sustained after the removal of the guest molecules. A novel bilayered coordination polymer with nanoporous channels [Ni 3(bix) 3(PTCO) 2 (H 2O) 4·6H 2O] n ( 1) has been synthesized and the permanent porosity of ( 1) is confirmed by N 2 adsorption isotherm measurement.
ISSN:1387-7003
1879-0259
DOI:10.1016/j.inoche.2010.01.025