Synthesis of bimetallic Co-Ni/ZnO nanoprisms (ZnO-NPr) for hydrogen-rich syngas production via partial oxidation of methane

• Published in: Journal of environmental chemical engineering Vol. 9; no. 6; p. 106887
• Main Authors: Javed, Ahad Hussain, Shahzad, Nadia, Butt, Faaz Ahmed, Khan, M. Abdullah, Naeem, Nida, Liaquat, Rabia, Khoja, Asif Hussain
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01-12-2021
• Subjects: H2 Production, Syngas; Partial oxidation of methane; ZnO Nanoprisms; H2 Production, Syngas; Partial oxidation of methane; ZnO Nanoprisms
• ISSN: 2213-3437; 2213-3437
• DOI: 10.1016/j.jece.2021.106887

The utilisation of methane (CH4) to produce syngas (H2, CO) via partial oxidation of methane (POM) is an attractive technique, as syngas is a very valuable entity to produce liquid fuels and fuel cell applications. This work presents the hydrothermal growth of ZnO nanoprisms (ZnO-NPr) in a dual solvent for a controlled structure. The Co-Ni loaded ZnO-NPr catalysts were obtained in an aqueous solution by wetness impregnation method and tested for POM for the first time. The synthesized catalysts were characterized by employing XRD, SEM-EDX, TGA and RAMAN spectroscopy for structural and morphological analysis. The catalysts were analyzed for POM at 850 °C and demonstrated high catalytic activity. It was observed that the catalytic activity of Co loaded ZnO-NPr, and Ni-Co loaded ZnO-NPr was more and demonstrated the stable behaviour for CH4 conversion in comparison to Ni loaded catalysts. The Co-Ni loaded ZnO-NPr has shown a high CH4 conversion (XCH4) (98%), and excellent stability over 56 h on stream. The average value of H2/CO for Co-Ni loaded ZnO-NPr was 2.11, above the theoretical value for POM. It is attributed to the better performance of catalyst towards the selectivity of H2 in reaction pathways.
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•ZnO nanoprisms (NPr) support was successfully synthesized by hydrothermal process.•Bimetallic loaded ZnO-NPr showed shape dependent support effect in POM.•The high reactivity shown due to better interaction of Co and surface of support.•The bimetallic loaded catalyst exhibited excellent stability in POM reaction up to 56 h.