Influence of the molar concentration of phosphoric acid solution on the properties of metakaolin-phosphate-based geopolymer cements

• Published in: Applied clay science Vol. 147; pp. 184 - 194
• Main Authors: Tchakouté, Hervé K., Rüscher, Claus H., Kamseu, Elie, Andreola, Fernanda, Leonelli, Cristina
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01-10-2017
• Subjects: Berlinite; Compressive strength; Geopolymer cements; Metakaolin; Microstructure; Phosphoric acid solutions; Metakaolin; Berlinite; Phosphoric acid solutions; Compressive strength; Geopolymer cements; Microstructure
• ISSN: 0169-1317; 1872-9053
• DOI: 10.1016/j.clay.2017.07.036

Six different phosphoric acid solutions with molar concentrations 4, 6, 8, 10, 12 and 14M were prepared by dilution of commercial phosphoric acid in distilled water. The obtained phosphoric acid solutions were used for producing metakaolin-phosphate-based geopolymer cements. These geopolymer cements were obtained by adding each fresh prepared phosphoric acid solution to metakaolin with a mass ratio phosphoric acid solution/metakaolin=0.80. It was observed in the infrared spectra of phosphoric acid solutions 8, 10, 12 and 14M, the absorption bands at 875–879 and 949–972cm−1 which are assigned to H2PO4−. The SEM images of geopolymer cements exhibit the presence of berlinite (AlPO4) which is dispersed in the matrix and contributes to enhancing the strength, whereas the geopolymer cements from phosphoric acid solution with 14M are heterogeneous microstructures. The compressive strength of phosphate-based geopolymer cements was between 36.4 and 93.8MPa; it increased with increasing the concentration of phosphoric acid solutions up to 10M. It can be concluded that the most convenient concentration of phosphoric acid solution required for producing phosphate-based geopolymer cements with good mechanical properties is around 10M.
Preparation of metakaolin-phosphate-based geopolymer cements. [Display omitted]
•Six concentrations of phosphoric acid were prepared by diluting commercial one in distilled water.•The obtained solutions were used for producing metakaolin-phosphate-based geopolymer cements.•The compressive strength of phosphate-based geopolymer cements was between 36.4 and 93.8 MPa.•The geopolymer cements from phosphoric acid solution with 14 M are heterogeneous microstructures.•The most convenient molarity of phosphoric acid required for producing geopolymers is around 10 M.