Growth Peculiarities and Properties of KR3F10 (R = Y, Tb) Single Crystals

• Published in: Crystals (Basel) Vol. 11; no. 3; p. 285
• Main Authors: Karimov, Denis N., Buchinskaya, Irina I., Arkharova, Natalia A., Ivanova, Anna G., Savelyev, Alexander G., Sorokin, Nikolay I., Popov, Pavel A.
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 01-03-2021
• Subjects: Bridgman method; Bridgman technique; bulk crystals; complex fluoride; Cooling; Crystal growth; Crystal lattices; Crystal structure; Crystallization; Electric power; Enthalpy; Fluorides; growth from the melt; Heaters; Hygroscopicity; Ion migration; KTb3F10; KY3F10; Methods; Optical properties; Overheating; Physical properties; Potassium fluoride; Room temperature; Scanning electron microscopy; Single crystals; Software; Solid solutions; Thermal conductivity; United States > US
• ISSN: 2073-4352; 2073-4352
• DOI: 10.3390/cryst11030285

Cubic KR3F10 (R = Y, Tb) single crystals have been successfully grown using the Bridgman technique. Growth of crystals of this type is complicated due to the hygroscopicity of potassium fluoride and melt overheating. The solution to the problem of oxygen-incorporated impurities has been demonstrated through the utilization of potassium hydrofluoride as a precursor. In this study, the crystal quality, structure features, and optical, thermal and electrophysical properties of KR3F10 were examined. Data on the temperature dependences of conductivity properties of KTb3F10 crystals were obtained for the first time. These crystals indicated thermal conductivity equal to 1.54 ± 0.05 Wm−1K−1 at room temperature caused by strong phonon scattering in the Tb-based crystal lattice. Ionic conductivities of KY3F10 and KTb3F10 single crystals were 4.9 × 10−8 and 1.2 × 10−10 S/cm at 500 K, respectively, and the observed difference was determined by the activation enthalpy of F− ion migration. Comparison of the physical properties of the grown KR3F10 crystals with the closest crystalline analog from the family of Na0.5−xR0.5+xF2+2x (R = Tb, Y) cubic solid solutions is reported.