Expedient Method for Oxidation of Alcohol by Hydrogen Peroxide in the Presence of Amberlite IRA 400 Resin (Basic) as Phase-Transfer Catalyst

Expedient Method for Oxidation of Alcohol by Hydrogen Peroxide in the Presence of Amberlite IRA 400 Resin (Basic) as Phase-Transfer Catalyst

Amberlite IRA 400 (strongly basic), a classical polymer imparts phase-transfer catalysis in the oxidation of primary and secondary alcohols by hydrogen peroxide to give excellent yields of the corresponding carbonyl compounds or carboxylic acids in acetonitrile solvent at reflux temperature in 4-6 h...

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Bibliographic Details
Published in:Synthetic communications Vol. 38; no. 9; pp. 1416 - 1424
Main Authors: Bhati, Nishi, Sarma, Kuladip, Goswami, Amrit
Format: Journal Article
Language:English
Published: Taylor & Francis 01-01-2008
Subjects:
Amberlite resin
oxidation
progesterone
sodium tungstate
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Summary:Amberlite IRA 400 (strongly basic), a classical polymer imparts phase-transfer catalysis in the oxidation of primary and secondary alcohols by hydrogen peroxide to give excellent yields of the corresponding carbonyl compounds or carboxylic acids in acetonitrile solvent at reflux temperature in 4-6 h. The catalytic system is inert to other susceptible oxidation sites such as carbon-carbon double bonds
ISSN:0039-7911
1532-2432
DOI:10.1080/00397910801916090