Asymmetric styrene dimerisation using mixed palladium–indium catalysts

Asymmetric styrene dimerisation using mixed palladium–indium catalysts

Catalysts formed in situ from mixtures of palladium acetate, indium(III) triflate and a chiral non-chelating bis(phosphite) ligand give good to excellent conversions and reasonable enantioselectivity in the asymmetric dimerisation of styrenes. Graphical Abstract

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Bibliographic Details
Published in:Tetrahedron Vol. 61; no. 41; pp. 9799 - 9807
Main Authors: Bedford, Robin B., Betham, Michael, Blake, Michael E., Garcés, Andrés, Millar, Sarah L., Prashar, Sanjiv
Format: Journal Article
Language:English
Published: Elsevier Ltd 10-10-2005
Subjects:
Catalysis
Dimerisation
Hydrovinylation
Indium
Palladium
Styrene
Hydrovinylation
Palladium
Catalysis
Indium
Styrene
Dimerisation
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Description
Summary:Catalysts formed in situ from mixtures of palladium acetate, indium(III) triflate and a chiral non-chelating bis(phosphite) ligand give good to excellent conversions and reasonable enantioselectivity in the asymmetric dimerisation of styrenes. Graphical Abstract
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2005.06.083