Measurement of the kinetics of adsorbed cinnoline by square-wave voltammetry
The standard redox reaction rate constant of cinnoline (1,2-benzodiazine) adsorbed to the mercury electrode in 0.9 mol L(-1) KNO(3) buffered to pH 7, 9.2, and 4.65 are k(s)=455+/-110 s(-1), 65+/-25 s(-1), and 300+/-75 s(-1), respectively.
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| Published in: | Analytical and bioanalytical chemistry Vol. 373; no. 8; pp. 777 - 780 |
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| Main Author: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
Germany
01-08-2002
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| Online Access: | Get full text |
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| Summary: | The standard redox reaction rate constant of cinnoline (1,2-benzodiazine) adsorbed to the mercury electrode in 0.9 mol L(-1) KNO(3) buffered to pH 7, 9.2, and 4.65 are k(s)=455+/-110 s(-1), 65+/-25 s(-1), and 300+/-75 s(-1), respectively. |
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| Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
| ISSN: | 1618-2642 1618-2650 |
| DOI: | 10.1007/s00216-002-1364-1 |