Behavior of Hydroxyl Groups in Quartz Glass during Heat Treatment in the Range 750–950°C

• Published in: Inorganic materials Vol. 54; no. 9; pp. 925 - 930
• Main Authors: Velmuzhov, A. P., Sukhanov, M. V., Churbanov, M. F., Kotereva, T. V., Shabarova, L. V., Kirillov, Yu. P.
• Format: Journal Article
• Language: English
• Published: Moscow Pleiades Publishing 2018; Springer Nature B.V
• Subjects: ACTIVATION ENERGY; ANNEALING; CHALCOGENIDES; Chemistry; Chemistry and Materials Science; CONCENTRATION RATIO; CONTROLLED ATMOSPHERES; DIFFUSION; Diffusion coefficient; Electric arc melting; FOURIER TRANSFORM SPECTROMETERS; Fourier transforms; GLASS; Heat treating; Heat treatment; HYDROGEN; Hydroxyl groups; HYDROXYL RADICALS; Industrial Chemistry/Chemical Engineering; INFRARED SPECTRA; Infrared spectroscopy; Inorganic Chemistry; MATERIALS SCIENCE; QUARTZ; REACTION KINETICS; Silica glass; TEMPERATURE RANGE 1000-4000 K; TUBES; quartz glass; diffusion; OH groups; IR spectroscopy
• ISSN: 0020-1685; 1608-3172
• DOI: 10.1134/S0020168518090169

The concentration of hydroxyl groups in different types of quartz glass tubes, the OH concentration profile across the tube wall, and the kinetics of OH removal during heat treatment in the temperature range 750–950°C have been studied by Fourier transform IR spectroscopy. For TK-I tubes, produced by vacuum electromelting of quartz, followed by annealing in a hydrogen atmosphere, we have calculated the diffusion coefficient of OH groups in this temperature range and the activation energy for diffusion: 215 ± 10 kJ/mol. We have found heat treatment conditions that ensure a considerable decrease in the concentration of OH groups in quartz tubes that are used in the fabrication of reactors for the preparation of extrapure chalcogenide glasses.