A Classical Silver Carbonyl Complex [{MeB[3-(Mes)pz]3}Ag(CO)] and the Related Silver Ethylene Adduct [{MeB[3-(Mes)pz]3}Ag(C2H4)]

A Classical Silver Carbonyl Complex [{MeB[3-(Mes)pz]3}Ag(CO)] and the Related Silver Ethylene Adduct [{MeB[3-(Mes)pz]3}Ag(C2H4)]

Sting in the tale: A thermally stable silver(I) ethylene complex and the first classical silver(I) carbonyl adduct (see structure) have been isolated using the nonfluorinated, relatively electron‐rich scorpionate ligand [MeB{3‐(Mes)pz}3]− (Mes=2,4,6‐trimethylphenyl, pz=pyrazolate).

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Bibliographic Details
Published in:Angewandte Chemie International Edition Vol. 46; no. 13; pp. 2188 - 2191
Main Authors: Rasika Dias, H. V., Fianchini, Mauro
Format: Journal Article
Language:English
Published: Weinheim WILEY-VCH Verlag 19-03-2007
WILEY‐VCH Verlag
Subjects:
alkene ligands
carbonyl ligands
coordination modes
N ligands
silver
Online Access:Get full text
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Description
Summary:Sting in the tale: A thermally stable silver(I) ethylene complex and the first classical silver(I) carbonyl adduct (see structure) have been isolated using the nonfluorinated, relatively electron‐rich scorpionate ligand [MeB{3‐(Mes)pz}3]− (Mes=2,4,6‐trimethylphenyl, pz=pyrazolate).
Bibliography:istex:704F7921A6BC09993B908F1C6196D10A1FCBA576
Robert A. Welch Foundation - No. Y-1289
H.V.R.D. thanks the Robert A. Welch Foundation (grant Y-1289) and the National Science Foundation (CHE-0314666) for financial support of this research. Mes=2,4,6-trimethylphenyl, pz=pyrazolate. Herein, we use abbreviations based on IUPAC guidelines, that is, ν for frequency and $\tilde \nu $ for wavenumber.
ark:/67375/WNG-RX9QTWZD-6
ArticleID:ANIE200604084
National Science Foundation - No. CHE-0314666
H.V.R.D. thanks the Robert A. Welch Foundation (grant Y‐1289) and the National Science Foundation (CHE‐0314666) for financial support of this research. Mes=2,4,6‐trimethylphenyl, pz=pyrazolate. Herein, we use abbreviations based on IUPAC guidelines, that is
for frequency and
tilde \nu
ν
for wavenumber.
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200604084