Transport of dissolved organic matters derived from biomass-pyrogenic smoke (SDOMs) and their effects on mobility of heavy metal ions in saturated porous media

• Published in: Chemosphere (Oxford) Vol. 336; p. 139247
• Main Authors: Chen, Jiuyan, Zhang, Huiying, Farooq, Usman, Zhang, Qiang, Ni, Jinzhi, Miao, Renhui, Chen, Weifeng, Qi, Zhichong
• Format: Journal Article
• Language: English
• Published: England Elsevier Ltd 01-09-2023
• Subjects: Biomass; Cations; Cu2; Dissolved Organic Matter; Dissolved organic matters; Metals, Heavy; Porosity; Porous media; Quartz - chemistry; Sand; Silicon Dioxide - chemistry; Smoke; Transport; Porous media; Cu2; Transport; Dissolved organic matters; Cu(2+)
• ISSN: 0045-6535; 1879-1298
• DOI: 10.1016/j.chemosphere.2023.139247

Biomass-pyrogenic smoke-derived dissolved organic matter (SDOMs) percolating into the underground environment profoundly impacts the transport and fate of environmental pollutants in groundwater systems. Herein, SDOMs were produced by pyrolyzing wheat straw at 300–900 °C to explore their transport properties and effects on Cu2+ mobility in quartz sand porous media. The results indicated that SDOMs exhibited high mobility in saturated sand. Meanwhile, the mobility of SDOMs was enhanced at a higher pyrolysis temperature due to the decrease in their molecular sizes and the declined H-bonding interactions between SDOM molecules and sand grains. Furthermore, the transport of SDOMs was elevated as pH values were raised from 5.0 to 9.0, which resulted from the strengthened electrostatic repulsion between SDOMs and quartz sand particles. More importantly, SDOMs could facilitate Cu2+ transport in the quartz sand, which stemmed from forming soluble Cu–SDOM complexes. Intriguingly, the promotional function of SDOMs for the mobility of Cu2+ was strongly dependent on the pyrolysis temperature. Generally, SDOMs generated at higher temperatures exhibited superior effects. The phenomenon was mainly due to the differences in the Cu-binding capacities of various SDOMs (e.g., cation-π attractive interactions). Our findings highlight that the high-mobility SDOM can considerably affect heavy metal ions' environmental fate and transport.
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•SDOMs exhibited excellent mobility in quartz sand over the pH range of 5.0–9.0•The molecular sizes of SDOMs and H-bonding interactions contributed to the mobility.•SDOMs facilitated Cu2+ mobility owing to the formation of soluble SDOM-Cu complexes.•The promotion effects of SDOMs strongly depended on the pyrolysis temperature.