Functionalized calix[4]arene-based receptor for saccharide recognition

Functionalized calix[4]arene-based receptor for saccharide recognition

A novel class of functionalized-calix[4]arene such as 1,4-dihydropyridine-calix[4]arene, acridine-calix[4]arene and pyrimidine-calix[4]arene were synthesized using multicomponent reaction. These compounds have been characterized by 1 H NMR, 13 C NMR and HRMS. Fluorescent and 1 H NMR titration invest...

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Bibliographic Details
Published in:Journal of inclusion phenomena and macrocyclic chemistry Vol. 83; no. 1-2; pp. 53 - 61
Main Authors: Mirza-Aghayan, Maryam, Yarmohammadi, Masoud, Mohammadian, Narges, Zadmard, Reza, Asadi, Fatemeh
Format: Journal Article
Language:English
Published: Dordrecht Springer Netherlands 01-10-2015
Subjects:
Chemistry
Chemistry and Materials Science
Crystallography and Scattering Methods
Food Science
Organic Chemistry
Original Article
Saccharide recognition
Multicomponent reaction
Fluorescent titration
Functionalized-calixarene
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Summary:A novel class of functionalized-calix[4]arene such as 1,4-dihydropyridine-calix[4]arene, acridine-calix[4]arene and pyrimidine-calix[4]arene were synthesized using multicomponent reaction. These compounds have been characterized by 1 H NMR, 13 C NMR and HRMS. Fluorescent and 1 H NMR titration investigations reveal that these derivatives have the high binding constant towards the monosaccharide and disaccharide in aqueous solution. The formation of complex was also supported by electrospray mass spectrometry.
ISSN:1388-3127
1573-1111
DOI:10.1007/s10847-015-0540-9