WCO biodiesel production by heterogeneous catalyst and using cadmium (II)-based supramolecular coordination polymer additives to improve diesel/biodiesel fueled engine performance and emissions

• Published in: Journal of thermal analysis and calorimetry Vol. 147; no. 11; pp. 6375 - 6391
• Main Authors: Elkelawy, Medhat, Etaiw, Safaa El-din H., Bastawissi, Hagar Alm-Eldin, Marie, Hassan, Radwan, Ahmed Mohamed, Dawood, Mohamed M., Panchal, Hitesh
• Format: Journal Article
• Language: English
• Published: Cham Springer International Publishing 01-06-2022; Springer; Springer Nature B.V
• Subjects: Additives; Air quality management; Alternative fuels; Analytical Chemistry; Biodiesel fuels; Biofuels; Biomass energy; Cadmium; Catalysts; Chemistry; Chemistry and Materials Science; Cooking; Coordination polymers; Diesel engines; Emissions; Esters; Innovations; Inorganic Chemistry; Measurement Science and Instrumentation; Nanomaterials; Nanoparticles; New technology; Nitrogen oxide; Norms; Physical Chemistry; Polymer industry; Polymer Sciences; Polymers; Reaction time; Thermodynamic efficiency; Titanium dioxide; Transesterification; Triglycerides; Nanoparticles; Waste cooking oil; CI engine; Emission; Heterogeneous catalyst; Combustion; Biodiesel
• ISSN: 1388-6150; 1588-2926
• DOI: 10.1007/s10973-021-10920-1

Recently, research organizations and researchers have been working on finding and producing clean and alternatives to fuels such as biofuels, and thus using new technologies to reduce harmful emissions such as nanoparticle technology. In this regard the use of heterogeneous catalyst for producing biodiesel is classified as a new promising technology as of its characterization for saving in the production total cost. Heterogeneous transesterification reaction is applied to change the waste cooking oil WCO triglycerides to methyl esters with applying lower concentration of alcohol, while the yielded biodiesel has fitted the ASTM norms. In the current investigation, the maximum biodiesel yield obtained was 95% at optimal reaction conditions of 60 min reaction time, 60 °C reaction temperature, 0.01 mass% TiO2 nano-catalyst, 0.3 mass% NaoH, and 1:10 V/V% oil to methanol percentage. Also, the influence of diesel, biodiesel blend, and Cadmium (II)-Based supramolecular coordination polymer nano-additives, {[Cd (EIN)2(SCN)2]}, SCP 1, on the performance and emissions of DI diesel engine were studied experimentally by varying the engine load at 1400 rpm. While the obtained results show a great reduction in UHC, CO, and NOx emissions with increasing the SCP 1 nanomaterials. However, the CO
2
emissions show a unique increase in its value by adding SCP 1 as a nanoparticle. If 70 ppm of SCP 1 is used the brake thermal efficiency (BTE) has reached 31.2% as associated with the tested fuels. Also, temperature of the engine exhaust (EGT) was analyzed for all tested fuels, where a consequent reduction was observed.