Crystal structure of palladium(II) complex with 2,2′-dipyridylamine and 4-toluenesulfonyl-L-serine

• Published in: Journal of structural chemistry Vol. 57; no. 3; pp. 534 - 541
• Main Authors: Mehdipour, E., Bahrami, H., Shamaei, S., Amani, V.
• Format: Journal Article
• Language: English
• Published: Moscow Pleiades Publishing 01-05-2016
• Subjects: Atomic; Atomic/Molecular Structure and Spectra; Chemistry; Chemistry and Materials Science; Inorganic Chemistry; Molecular; Optical and Plasma Physics; Physical Chemistry; Solid State Physics; 2,2′-dipyridylamine; differential thermal analyses; 4-toluenesulfonyl-L-serine; luminescent properties; thermal gravimetric; crystal structure; palladium(II) complex
• ISSN: 0022-4766; 1573-8779
• DOI: 10.1134/S0022476616030161

The [Pd(dpa)(tsser)] complex (
1
) is prepared from the reaction of PdCl
2
and 2,2′-dipyridylamine (dpa) with 4-toluenesulfonyl-L-serine (tsserH
2
). This complex is characterized by spectral methods (IR, UV-Vis,
1
H NMR, and luminescence), elemental analysis, thermal analysis (TG, DTA), and single crystal X-ray diffraction. X-ray structure determinations show that in this complex, Pd
II
atoms are four-coordinated in a distorted square-planar configuration by two N atoms from a bidentate 2,2′-dipyridylamine ligand and one N atom and one O atom from a bidentate tsser
2–
ligand.