Microwave Spectrum, Quadrupole Coupling Constants, and Dipole Moments of 1-Chloro-2-fluorobenzene

Microwave Spectrum, Quadrupole Coupling Constants, and Dipole Moments of 1-Chloro-2-fluorobenzene

The microwave spectrum of 1-chloro-2-fluorobenzene has been reinvestigated in the frequency region 7–14 GHz by a molecular beam Fourier transform microwave spectrometer. A least-squares analysis of the observeda- andb-type transition frequencies gave rotational and quartic centrifugal distortion con...

Full description

Saved in:
Bibliographic Details
Published in:Journal of molecular spectroscopy Vol. 176; no. 1; pp. 17 - 22
Main Authors: Onda, Masao, Odaka, Tsuaki, Miyazaki, Hideya, Mori, Masayoshi, Yamaguchi, Ichiro, Niide, Yuzuru
Format: Journal Article
Language:English
Published: Elsevier Inc 01-03-1996
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The microwave spectrum of 1-chloro-2-fluorobenzene has been reinvestigated in the frequency region 7–14 GHz by a molecular beam Fourier transform microwave spectrometer. A least-squares analysis of the observeda- andb-type transition frequencies gave rotational and quartic centrifugal distortion constants and the components of the nuclear quadrupole coupling tensor in the principal inertial axis system[formula]for 1-[35Cl]chloro-2-fluorobenzene. The dipole moments were determined to be μa= 2.28(85)D and μb= 1.47(30)D.
ISSN:0022-2852
1096-083X
DOI:10.1006/jmsp.1996.0056