Dielectric, electrical and optical properties of a Ni-substituted double perovskite ceramic

• Published in: Ferroelectrics Vol. 618; no. 1; pp. 259 - 273
• Main Authors: Mohanty, S., Behera, S.
• Format: Journal Article
• Language: English
• Published: Philadelphia Taylor & Francis 02-01-2024; Taylor & Francis Ltd
• Subjects: ac conductivity; Ceramics; Coercivity; Dielectric properties; Electrical properties; Energy gap; Energy storage; Ferroelectricity; Ferromagnetism; Frequency variation; High temperature; Hopping conduction; Hysteresis loops; M-H loop; Optical properties; P-E loop; Perovskites; Photovoltaics; Room temperature; SEM; Temperature dependence; UV-Visible; XRD
• ISSN: 0015-0193; 1563-5112
• DOI: 10.1080/00150193.2023.2271331

In this report, iron based double perovskite oxide Ca
2
Fe
0.85
Ni
0.15
NbO
6
was successfully synthesized adopting the solid state reaction method. The structure and microstructure along with the purity, frequency and temperature dependent dielectric properties, energy storage and band gap modulation properties of the ceramic is also discussed. The ceramic shows a small band gap with a high remnant polarization which aligns it toward ferroelectric photovoltaic device applications. The temperature stable dielectric constant of the material up to a high temperature range is useful for MLCC applications. The energy storage density of the material is calculated from room temperature hysteresis loop. The frequency variation of ac conductivity refers Jonscher's law. The temperature variation of frequency exponent term n indicates CBH (correlated barrier hopping), model of the conduction mechanism in the sample. The presence of room temperature M-H loop with negligible magnetization and coercive value indicates the soft ferromagnetic behavior of the ceramic.