Novel Synthesis of Borane Complexes of Cyclic Phosphanes Using Ruthenium-Catalyzed Olefin Metathesis

Grubbs' catalyst [Cl2Ru{P(C6H11)3}2=CHPh] can be used to synthesize borane complexes of cyclic phosphanes by ring‐closing metathesis reactions. This strategy has been applied, for example, to the preparation of a borane‐protected bisphosphanes [Eq. (1)].

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Bibliographic Details
Published in:	Angewandte Chemie International Edition Vol. 39; no. 14; pp. 2491 - 2493
Main Authors:	Schuman, Marc, Trevitt, Michael, Redd, Andrew, Gouverneur, Véronique
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag GmbH 17-07-2000 WILEY‐VCH Verlag GmbH
Subjects:	boranes metathesis P ligands phosphane
Online Access:	Get full text
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Description
Summary:	Grubbs' catalyst [Cl2Ru{P(C6H11)3}2=CHPh] can be used to synthesize borane complexes of cyclic phosphanes by ring‐closing metathesis reactions. This strategy has been applied, for example, to the preparation of a borane‐protected bisphosphanes [Eq. (1)].
Bibliography:	istex:6E89DDE8AFF68A9D01D6031CFFE29358076969F0 ark:/67375/WNG-M9DZ8JFR-X ArticleID:ANIE2491 This work was supported by the European Community Training and Mobility Research Programme (COSSAC, ERBFMRXCT 980193 to M.S.) and by the Nuffield Foundation (NAL/00046/G).
ISSN:	1433-7851 1521-3773
DOI:	10.1002/1521-3773(20000717)39:14<2491::AID-ANIE2491>3.0.CO;2-H