Self-organisation in P-substituted guanidines leading to solution-state isomerisation

Different isomeric forms of the amidine unit have been identified in Ph2P(E)C[NR'][NHR'] (E = S, Se; R' = iPr, Cy), using both solid- and solution-state techniques.

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Bibliographic Details
Published in:	Chemical communications (Cambridge, England) no. 21; p. 2410
Main Authors:	Grundy, Joanna, Coles, Martyn P, Avent, Anthony G, Hitchcock, Peter B
Format:	Journal Article
Language:	English
Published:	England 07-11-2004
Subjects:	Guanidines - chemistry Models, Molecular Molecular Structure Organometallic Compounds - chemistry Phosphorus - chemistry Selenium - chemistry Stereoisomerism
Online Access:	Get more information
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Description
Summary:	Different isomeric forms of the amidine unit have been identified in Ph2P(E)C[NR'][NHR'] (E = S, Se; R' = iPr, Cy), using both solid- and solution-state techniques.
ISSN:	1359-7345
DOI:	10.1039/b410041g