Trace and major elements in geological samples from Itingusssú River Basin, Sepetiba Bay––Rio de Janeiro

• Published in: Journal of radioanalytical and nuclear chemistry Vol. 290; no. 2; pp. 381 - 389
• Main Authors: Araripe, D. R., Bellido, A. V. B., Patchineelam, S. R., Latini, R. M., Bellido, L. F., Fávaro, D. I. T.
• Format: Journal Article
• Language: English
• Published: Dordrecht Springer Netherlands 01-11-2011
• Subjects: Brazil; Chemistry; Chemistry and Materials Science; Diagnostic Radiology; Enrichment; Hadrons; Heavy Ions; Inorganic Chemistry; Nuclear Chemistry; Nuclear Physics; Physical Chemistry; River basins; Samples; Sediments; Soil (material); Statistical analysis; Statistical methods; Rare earth elements; Sediments; Trace elements
• ISSN: 0236-5731; 1588-2780
• DOI: 10.1007/s10967-011-1220-x

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The Itingussú drainage basin is situated at 22°44′–22°55′ SL and 44°53′–43°55′ WL, in Coroa-Grande district, Sepetiba Bay, southwest of Rio de Janeiro, Brazil. Its total area is less than 10 km
2
and includes a waterfall with three drop offs. The study area is located in a granitic pre-Cambrian embasement, discharging in a mangrove forest fringe. This work attempts to investigate the influence of lithology types in the elemental composition of soil of region and sediments of related mangrove. Instrumental neutron activation analysis and subsequent gamma-ray spectrometry were used. This technique enabled the measurement of at least twenty-one chemical elements. The more representative soil samples were enriched with U and Th. Multivariate Statistical Analysis showed that the soil and sediments formed in this area have been influenced by the leucocratic rocks, enriched with LREE and Th. The factorial analysis enables the identification of five factors of influence in the ordination of elements: presence of iron minerals (biotite); presence of allanite; marine influence in the sediment; differentiated kinetic of transport and diagenesis.