Two- and Three-Dimensional Polymeric Co(II) Terephthalates with 3,3',5,5'-Tetrabromo-4,4'-bipyridine (3,3'5,5'-BrBipy)

• Published in: Russian journal of coordination chemistry Vol. 50; no. 1; pp. 67 - 72
• Main Authors: Sakhapov, I. F., Zagidullin, A. A., Islamov, D. R., Sharutin, V. V., Yakhvarov, D. G., Zherebtsov, D. A., Milyukov, V. A., Zaguzin, A. S., Fedin, V. P., Adonin, S. A.
• Format: Journal Article
• Language: English
• Published: Moscow Pleiades Publishing 2024; Springer Nature B.V
• Subjects: Chemistry; Chemistry and Materials Science; Inorganic Chemistry; Metal-organic frameworks; Physical Chemistry; Terephthalic acid; cobalt; X-ray diffraction analysis; linker ligands; metal-organic frameworks
• ISSN: 1070-3284; 1608-3318
• DOI: 10.1134/S1070328423700707

The reaction of 3,3',5,5'-tetrabromo-4,4'-bipyridine (BrBipy) with cobalt nitrate and terephthalic acid (H
2
Bdc) gave 2D and 3D metal-organic frameworks {[Co
2
(Bdc)
2
(BrBipy)
2
(H
2
O)
4
]·4DMF} (
I
) and {[Co
2
(Ddc)
4
(BrDipy)]·2MeOH} (
II
), respectively. The structure of the complexes was studied by X-ray diffraction (CCDC nos. 2259216 (
I
) and 2259214) (
II
)).