Cadmium(II) Metal-Organic Frameworks Based on Iodine-Substituted Terephthalic Acid Derivatives and 1,1'-(1,4-Butanediyl)-bis-imidazole

• Published in: Russian journal of coordination chemistry Vol. 50; no. 1; pp. 61 - 66
• Main Authors: Bondarenko, M. A., Zaguzin, A. S., Abramov, P. A., Korol’kov, I. V., Zherebtsov, D. A., Fedin, V. P., Adonin, S. A.
• Format: Journal Article
• Language: English
• Published: Moscow Pleiades Publishing 2024; Springer Nature B.V
• Subjects: Chemistry; Chemistry and Materials Science; Imidazole; Inorganic Chemistry; Iodine; Metal-organic frameworks; Physical Chemistry; Terephthalic acid; cadmium; carboxylates; X-ray diffraction analysis; metal-organic frameworks
• ISSN: 1070-3284; 1608-3318
• DOI: 10.1134/S1070328423700689

Two metal-organic frameworks based on Cd(II) and 2-iodo-(2-I-Bdc) and 2,5-diodo-(2,5-I-Bdc)terephthalate were obtained: {[Cd(2-I-Bdc)(Bbi)]} (
I
) and {[Cd2(2,5-I-Bdc)2(DMF)2(Bbi)]} (
II
) (Bbi = 1,1'-(1,4-butanediyl)bis(imidazole)). The structures of both complexes were established by X-ray diffraction (CCDC no. 2258217 (
I
) and 2257566 (
II
)).