Rice husk coated with copper oxide nanoparticles for 17α-ethinylestradiol removal from an aqueous solution: adsorption mechanisms and kinetics

• Published in: Environmental monitoring and assessment Vol. 195; no. 9; p. 1078
• Main Authors: Alhares, Hasanain Saad, Ali, Qahtan Adnan, Shaban, Mohammed Ali A., M-Ridha, Mohanad J., Bohan, Hawraa R., Mohammed, Sabah J., Abed, Khalid M., Hasan, Hassimi Abu
• Format: Journal Article
• Language: English
• Published: Cham Springer International Publishing 01-09-2023; Springer Nature B.V
• Subjects: Adsorption; Aqueous solutions; Atmospheric Protection/Air Quality Control/Air Pollution; Chemisorption; Coatings; Copper; Copper oxides; Earth and Environmental Science; Ecology; Ecotoxicology; Endothermic reactions; Environment; Environmental Management; Environmental monitoring; Environmental science; Estrogens; Ethinylestradiol; Functional groups; Kinetics; Mathematical models; Monitoring/Environmental Analysis; Nanoparticles; Oestrogens; Parameter identification; Parameters; Removal; Rice; Sex hormones; Sorbents; Surface chemistry; Coating rice husk; 17α-Ethinylestradiol; Adsorption; CuO nanoparticles; Thermodynamic
• ISSN: 0167-6369; 1573-2959
• DOI: 10.1007/s10661-023-11689-6

The 17 α-ethinylestradiol (EE2) adsorption from aqueous solution was examined using a novel adsorbent made from rice husk powder coated with CuO nanoparticles (CRH). Advanced analyses of FTIR, XRD, SEM, and EDSwere used to identify the classification parameters of a CRH-like surface morphology, configuration, and functional groups. The rice husk was coated with CuO nanoparticles, allowing it to create large surface area materials with significantly improved textural qualities with regard to functional use and adsorption performance, according to a detailed characterization of the synthesized materials. The adsorption process was applied successfully with elimination effectiveness of 100% which can be kept up to 61.3%. The parameters of adsorption were affecting the adsorption process significantly. Thermodynamic data stated that the process of adsorption was endothermic, spontaneous, chemisorption and the molecules of EE2 show affinity with the CRH. It was discovered that the adsorption process controlled by a pseudo-second–order kinetic model demonstrates that the chemisorption process was controlling EE2 removal. The Sips model is regarded as optimal for representing this practice, exhibiting a significantly high determination coefficient of 0.948. This coefficient implies that the adsorption mechanism indicates the occurrence of both heterogeneous and homogeneous adsorption. According to the findings, biomass can serve as a cheap, operative sorbent to remove estrogen from liquified solutions.