Synthesis of thin superconducting HgBa2CaCu2O6+δ films by post-annealing of laser-ablated precursors

Superconducting HgBa2CaCu2O6+δ (Hg-1212) thin films have been prepared by laser ablation followed by post-annealing at high temperatures. Two synthesis methods were investigated, using (1) direct reaction of Hg–Ba–Ca–Cu–O precursor films in a Hg-controlled ambience, and (2) thermal diffusion of Hg i...

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Bibliographic Details
Published in:Journal of materials research Vol. 13; no. 3; pp. 557 - 564
Main Authors: Brazdeikis, A., FlodstrÖm, A. S., Bryntse, I.
Format: Journal Article
Language:English
Published: New York, USA Cambridge University Press 01-03-1998
Online Access:Get full text
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Summary:Superconducting HgBa2CaCu2O6+δ (Hg-1212) thin films have been prepared by laser ablation followed by post-annealing at high temperatures. Two synthesis methods were investigated, using (1) direct reaction of Hg–Ba–Ca–Cu–O precursor films in a Hg-controlled ambience, and (2) thermal diffusion of Hg into Ba–Ca–Cu–O precursor films in a controlled atmosphere containing both Hg- and Tl-bearing species. Effects of the annealing temperature, time, and bulk material composition on the Hg-1212 film and residual impurities are presented. Surface morphologies, growth defects, and transport properties of Hg-1212 on SrTiO3 substrates are discussed. Formation of Hg-1212 films on MgO and LaAlO3 substrates is briefly described.
Bibliography:istex:0307C8546D6C5CE1E93942A2846A2458DD949949
ArticleID:04308
PII:S0884291400043089
ark:/67375/6GQ-2ZSL500D-W
ObjectType-Article-2
SourceType-Scholarly Journals-1
ObjectType-Feature-1
content type line 23
ISSN:0884-2914
2044-5326
DOI:10.1557/JMR.1998.0071