Nanocrystallization and Core-loss properties of Fe-rich FeSiBPNbCu nanocrystalline alloy

• Published in: Journal of magnetism and magnetic materials Vol. 552; p. 169228
• Main Authors: Murugaiyan, Premkumar, Mitra, Amitava, Roy, Rajat K., Panda, Ashis K
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 15-06-2022; Elsevier BV
• Subjects: Amorphous structure; Annealing; Core loss; Crystallites; Crystallization; Eddy currents; Fe-amorphous; Hysteresis; Iron; Magnetic properties; Melt spinning; Nanoalloys; Nanocrystalline; Nanocrystals; Precursors; Quenching; Raw materials; Ribbons; Soft-magnetic; Thickness; Core-loss; Melt-spinning; Soft-magnetic; Fe-amorphous; Hysteresis; Nanocrystalline
• ISSN: 0304-8853; 1873-4766
• DOI: 10.1016/j.jmmm.2022.169228

•25 mm melt-spun ribbon of different thickness prepared using commercial raw materials.•Ribbon thickness influences amorphous matrix structure & nanocrystallization process.•Hysteresis contribution dominates sub-kHz Core-loss properties.•Low Core Loss P ≤ 0.4 W/kg @50 Hz/1.6 T is achieved.
The present work investigates the structure, soft-magnetic and core-loss properties of 25 mm wide Fe83Si2B9P4Nb1Cu1 nanocrystalline ribbons. The melt-spun precursor ribbons of the thickness of 22 and 28 µm were prepared using commercial raw materials under ambient atmosphere. The XRD and DSC results show predominantly amorphous and hetero-amorphous structure for 22 and 28 µm ribbons in the as-quenched state. Further, the partial crystallization annealing leads to thickness dependent nanocrystallization process, wherein the thinner 22 µm ribbon shows sluggish primary(α-Fe(Si)) and delayed secondary(Fe3(B0.8P0.2)) crystallization process compared to 28 µm ribbons. The difference is explained through as-quenched precursor matrix structure and selective solute re-distribution of the intergranular region during nanocrystallization. Moreover, the higher crystallite size (D) and volume fraction(Vcr) of α-Fe(Si) nanocrystallites are observed for the 28 µm ribbon in the optimal annealing window. Under optimal annealing conditions, the 28 µm nanocrystalline ribbon (733 K) shows better AC soft-magnetic properties including B800 of 1.62 T, Hc of 15.7 A/m, Br/Bs ratio ≥ 0.8 compared to B800 of 1.59 T, Hc of 17 A/m and Br/Bs ratio ≥ 0.7 of 22 µm (743 K) ribbon. The 28 µm ribbon shows a low core loss (P) of 0.34 W/kg under 50 Hz, 1.5 T compared to P > 0.65 W/kg for 22 µm ribbons. The lower core-loss behaviour of thicker 28 µm in the sub-kHz frequency regime has been explained based on the nanocrystalline microstructure and loss coefficients (hysteresis and eddy current). The work compares the AC core-loss properties with reported Fe-rich nanocrystalline alloys and also discusses the scope of improving B800 beyond 1.65 T for the present alloys.