Stereodirectional synthesis of the main component of pheromone (9Z,12E)-tetradeca-9,12-dienyl acetate by cross-coupling

Stereodirectional synthesis of the main component of pheromone (9Z,12E)-tetradeca-9,12-dienyl acetate by cross-coupling

By cross-coupling of alkynyl cuprate with crotyl halides was synthesized (9Z,12E)-tetradeca-9-12-dienyl acetate, the main component of pheromones of several insect species Lepidoptera. The assignment of the chemical shifts of diene system was performed by1H and13NMR spectroscopy.

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Bibliographic Details
Published in:Russian journal of electrochemistry Vol. 36; no. 6; pp. 765 - 770
Main Authors: Matveeva, E. D., Erin, A. S., Leshcheva, I. F., Kurts, A. L.
Format: Journal Article
Language:English
Published: New York Springer Nature B.V 01-06-2000
Subjects:
Cross coupling
Halides
Insects
Online Access:Get full text
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Description
Summary:By cross-coupling of alkynyl cuprate with crotyl halides was synthesized (9Z,12E)-tetradeca-9-12-dienyl acetate, the main component of pheromones of several insect species Lepidoptera. The assignment of the chemical shifts of diene system was performed by1H and13NMR spectroscopy.
ISSN:1023-1935
1608-3342
DOI:10.1007/BF02757427