Unraveling the degradation of levofloxacin using highly efficient β-cyclodextrin-modified copper ferrite through peroxymonosulfate activation: Mechanistic performance and degradation pathways

• Published in: Journal of molecular liquids Vol. 404; p. 124978
• Main Authors: Ul Rehman, Faisal, Iqbal, Amjad, Khalid, Awais, Dib, Hanna, Nawaf Albalawi, Aisha, Ahmed, Adeel, Usman, Muhammad, Ismail, Mohamed A.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 15-06-2024
• Subjects: Catalytic degradation; CuFe2O4@β-CD catalysts; Degradation pathways; Levofloxacin (LEV); Peroxymonosulfate activation; CuFe2O4@β-CD catalysts; Levofloxacin (LEV); Catalytic degradation; Peroxymonosulfate activation; Degradation pathways
• ISSN: 0167-7322; 1873-3166
• DOI: 10.1016/j.molliq.2024.124978

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•CuFe2O4@β-CD composites were fabricated through the hydrothermal method and employed as a PMS activator.•Levofloxacin (LEV) degradation using CuFe2O4@β-CD/PMS reached 98.87 % in 24 min.•LEV abatement in the CuFe2O4@β-CD/PMS system was accomplished via radical and non-radical pathways.•The conversion of Fe3+/Fe2+ and Cu+/Cu2+ pairs produced the SO4•−, •OH, and 1O2 liable for LEV degradation.•CuFe2O4@β-CD exhibited high stability, reusability, and low metal leaching after five consecutive cycles.
In this study, a highly magnetic β-cyclodextrin-modified copper ferrite (CuFe2O4@β-CD) catalyst was developed utilizing a hydrothermal method, which was subsequently utilized to degrade Levofloxacin (LEV) antibiotic in aqueous solution via heterogeneous activation of peroxymonosulfate (PMS). The findings demonstrated that the 98.87 % degradation of LEV was achieved with CuFe2O4@β-CD/PMS, much higher than that of pure CuFe2O4/PMS (87.78 %) within a 24-minute time frame under optimal parameters ([CuFe2O4@β-CD] = 0.4 g/L, [PMS] = 0.4 mM, [LEV] = 25 mg/L, pH = 6), and CuFe2O4@β-CD/PMS was present. The rate constant of CuFe2O4@β-CD/PMS (0.1608 min−1) was much greater than that of the CuFe2O4/PMS system (0.0822 min−1). The increased availability of active sites for PMS activation may be credited to the larger surface area (189.42 m2/g) of the CuFe2O4@β-CD catalyst in comparison to the pristine CuFe2O4 (87.76 m2/g), which facilitated the improved degradation of LEV. Additionally, the impact of various reaction parameters and intervening anions on the degradation of LEV was investigated. The emergence of free radicals (SO4•−, •OH, and 1O2) was corroborated via electron paramagnetic resonance and scavenging experiments. On the basis of recognizing reaction intermediates, a hypothetical degradation mechanism for LEV was developed. PMS activation was caused by the transformation of Cu+/Cu2+ and Fe3+/Fe2+ pairs, which was accomplished via radical and non-radical pathways. Also, CuFe2O4@β-CD demonstrated exceptional stability and retained its catalytic activity after five concurrent cycles. In conclusion, the CuFe2O4@β-CD catalyst demonstrated encouraging potential in the context of purifying LEV-contaminated water.