Barbier-type Carbonyl-allylation with Allyl Compounds and SnCl2 in the Presence of PdCl2[PPh2(m-C6H4SO3Na)]2 under Two-phase Conditions
The hydrophilic palladium complex efficiently catalyzes the allylation of carbonyl compounds with allyl chlorides or allyl alcohols and SnCl2 under aqueous-organic biphase conditions, which allow us easily to separate the product and to recover the organic solvent from the reaction mixture.
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| Published in: | Chemistry letters Vol. 27; no. 1; pp. 5 - 6 |
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| Main Authors: | , , |
| Format: | Journal Article |
| Language: | English |
| Published: |
Tokyo
The Chemical Society of Japan
01-01-1998
Chemical Society of Japan |
| Online Access: | Get full text |
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| Summary: | The hydrophilic palladium complex efficiently catalyzes the allylation of carbonyl compounds with allyl chlorides or allyl alcohols and SnCl2 under aqueous-organic biphase conditions, which allow us easily to separate the product and to recover the organic solvent from the reaction mixture. |
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| ISSN: | 0366-7022 1348-0715 |
| DOI: | 10.1246/cl.1998.5 |