Preliminary communication - The synthesis and thermotropic liquid crystalline behaviour of novel main chain poly(aryl ether ketone)s containing a lateral phenyl group

• Published in: Liquid crystals Vol. 24; no. 2; pp. 311 - 314
• Main Authors: ZHANG, SHANJU, ZHENG, YUBIN, WU, ZHONGWEN, TIAN, MINGWEN, YANG, DECAI, YOSOMIYA, RYUTOKU
• Format: Journal Article
• Language: English
• Published: Taylor & Francis Group 01-02-1998
• ISSN: 0267-8292; 1366-5855
• DOI: 10.1080/026782998207488

Novel main chain poly(aryl ether ketone)s containing a lateral phenyl group were synthesized by nucleophilic substitution reactions of 4,4-biphenol and phenylhydroquinone with either 4,4-difluorobenzophenone or 1,4-bis(4-fluorobenzoyl)benzene and their thermotropic liquid crystalline properties were characterized by a variety of experimental techniques. Thermotropic liquid crystalline behaviour was observed in the copolymers containing 50 and 70 mol% biphenol. Melting (Tm) and isotropization (Ti) transitions both appeared on the DSC thermograms. A banded texture was formed after shearing the sample in the liquid crystalline nematic state. As expected, each of the copolymers had a relatively lower melting transition than the biphenol-based homopoly(aryl ether ketone)s because of the copolymerization effect of the crystal-disrupting monomer phenylhydroquinone.