Optical temperature sensing behavior of Dy3+-doped transparent alkaline earth fluoride glass ceramics

Dy 3+ -doped transparent BaF 2 , CaF 2 , and SrF 2 glass ceramics were fabricated, respectively, by a melt-quenching method, and their structures of resulting alkaline earth fluoride glass ceramics are studied by the X-ray diffraction and transmission electron microscopy. Temperature-dependent spect...

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Bibliographic Details
Published in:Applied physics. A, Materials science & processing Vol. 123; no. 5; pp. 1 - 8
Main Authors: Bu, Y. Y., Wang, Y. M., Yan, X. H.
Format: Journal Article
Language:English
Published: Berlin/Heidelberg Springer Berlin Heidelberg 01-05-2017
Springer Nature B.V
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Summary:Dy 3+ -doped transparent BaF 2 , CaF 2 , and SrF 2 glass ceramics were fabricated, respectively, by a melt-quenching method, and their structures of resulting alkaline earth fluoride glass ceramics are studied by the X-ray diffraction and transmission electron microscopy. Temperature-dependent spectra, thermal quenching ratios, sensitivity are studied systematically in three kinds of glass ceramics. Using fluorescence intensity ratio method, the 4 I 15/2 and 4 F 9/2 of Dy 3+ ions are verified as thermally coupled energy levels. A new fitting method to establish the relation between fluorescence intensity ratios and temperature has been developed to reduce the error value of sensitivity. It is found that the values of sensor sensitivity S R are dependent on host types, and the maximum S R  = 0.00032 K −1 is obtained at T  = 576.5 K in Dy 3+ -doped transparent SrF 2 glass ceramics.
ISSN:0947-8396
1432-0630
DOI:10.1007/s00339-017-0949-7