Application of zirconium aspartic acid metal-organic framework (MIP-202(Zr)) for high efficient ruthenium adsorption from aqueous solutions

• Published in: Applied radiation and isotopes Vol. 213; p. 111461
• Main Authors: Zuba, I., Ponomareva, O. Yu, Vershinina, T.N., Vinogradov, I.I., Korneeva, E.A., Hetmańczyk, J., Pawlukojć, A.
• Format: Journal Article
• Language: English
• Published: England Elsevier Ltd 01-11-2024
• Subjects: Adsorption capacity; Adsorption mechanism; MIP-202(Zr); Ruthenium ions; Ruthenium sorption; Adsorption capacity; MIP-202(Zr); Ruthenium sorption; Ruthenium ions; Adsorption mechanism
• ISSN: 0969-8043; 1872-9800; 1872-9800
• DOI: 10.1016/j.apradiso.2024.111461

The zirconium metal – organic framework MIP-202(Zr), based on L-aspartic acid, was prepared by hydrothermal method and used for study of ruthenium adsorption from aqueous solutions. The obtained material was characterized by X-ray diffraction (XRD), infra red spectroscopy (IR), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The batch adsorption experiment was performed for determination of adsorption equilibrium, kinetics and thermodynamics parameters to Ru(III) from aqueous solution on MIP-202(Zr). The data of ruthenium sorption onto MIP-202(Zr) were fitted and analyzed by the Langmuir, Freundlich and Temkin equilibrium isotherm models, while the Langumir adsorption isotherm models fit the best. Kinetic data were analyzed by four kinetic models, and ruthenium sorption on MIP202(Zr) can be describes the best by intra particle diffusion (Weber Morris). Analysis of thermodynamic properties of ruthenium ions sorption onto MIP-202(Zr) shows that the sorption process has a spontaneous and endothermic nature and is energetically beneficial.
•The zirconium metal – organic framework MIP-202(Zr), based on L-aspartic acid, was prepared by hydrothermal method and used for Ru-103 adsorption.•The adsorption isotherm, kinetic and thermodynamic parameters of Ru(III) onto MIP-202 (Zr) were studied by a batch adsorption system.•The Langmuir adsorption isotherm models fit the best for adsorption of Ru on MIP-202 (Zr).•The adsorption kinetic data obtained for Ru(III) can be described by intra particle diffusion model.•The adsorption process of Ru(III) on MIP-202(Zr) was found to be spontaneous and thermodynamically preferable.