Insertion of Ruthenium into an inorganic, cyclic biradicaloid

The reaction between [Ru2Cl2(μ2‐Cl)2(CO)6] and the biradicaloid [P(μ‐NTer)]2 proceeds under insertion of a Ru(II)Cl(CO)2 fragment into one P−N bond and addition of chloride to the adjacent phosphorus center. Thereby an unprecedented inorganic ruthenacycle is obtained that was investigated by single...

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Bibliographic Details
Published in:	Zeitschrift für anorganische und allgemeine Chemie (1950) Vol. 648; no. 17
Main Authors:	Oswald, Jan, Scharnhölz, Moritz T., Coburger, Peter, Beer, Henrik, Bresien, Jonas, Schulz, Axel, Grützmacher, Hansjörg
Format:	Journal Article
Language:	English
Published:	Weinheim Wiley Subscription Services, Inc 13-09-2022
Subjects:	Carbon monoxide Coordination chemistry Infrared spectroscopy Insertion Metallacycles N,P ligands NMR Nuclear magnetic resonance Phosphorus heterocycles Ruthenium Single crystals
Online Access:	Get full text
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Summary:	The reaction between [Ru2Cl2(μ2‐Cl)2(CO)6] and the biradicaloid [P(μ‐NTer)]2 proceeds under insertion of a Ru(II)Cl(CO)2 fragment into one P−N bond and addition of chloride to the adjacent phosphorus center. Thereby an unprecedented inorganic ruthenacycle is obtained that was investigated by single crystal X‐ray analysis, NMR and IR spectroscopy and DFT calculations. The reactivity of the complex in a halide‐pseudo‐halide exchange reaction and a coordination reaction were investigated.
Bibliography:	These authors contributed equally to this work.
ISSN:	0044-2313 1521-3749
DOI:	10.1002/zaac.202200093