Dielectric and Piezoelectric Properties of Mn-Doped Bi(Mg1/2Ti1/2)O3-PbTiO3 Piezoelectric Single Crystals with MPB Composition

• Published in: Crystals (Basel) Vol. 12; no. 5; p. 567
• Main Authors: Liu, Jinfeng, Xu, Guisheng, Zhu, Xiu, Chen, Meilin
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 01-05-2022
• Subjects: Bismuth; BMT-PT; Composition; Crystal growth; Crystal structure; Curie temperature; Dielectric loss; Dielectric properties; Ferroelectricity; High temperature; Hysteresis loops; MPB; Phase transitions; piezoelectric properties; Piezoelectricity; Room temperature; Single crystals
• ISSN: 2073-4352; 2073-4352
• DOI: 10.3390/cryst12050567

Mn-doped BMT-PT single crystals were grown using a flux method. The crystals were irregular and 4–10 mm in size. The EPMA and XRD results showed that the composition of the crystals was in the range of MPB. The room temperature dielectric permittivity εr and dielectric loss tanδ were 806 and 3.4% at 1 KHz. As the temperature increased, the rhombohedral phase did not first transform into the tetragonal phase, but transformed into the cubic phase directly. Owing to the Mn-doping, the ferroelectric hysteresis loops of the sample were quite narrow. The Curie temperature Tc, piezoelectric coefficient d33 and thickness electromechanical coupling factor kt of the single crystals along the direction were 464 °C, 392 pC/N and 0.51, respectively. The piezoelectric properties are much better than the values of the ceramics and the undoped BMT-PT single crystals with a MPB composition.