Selective hydrogenation of α,β-unsaturated aldehydes over Pt supported on cerium–zirconium mixed oxide of different composition

• Published in: Mendeleev communications Vol. 32; no. 4; pp. 488 - 491
• Main Authors: Vikanova, Kseniia V., Redina, Elena A., Kapustin, Gennady I., Mishin, Igor V., Davshan, Nikolay A., Kustov, Leonid M.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01-07-2022
• Subjects: cerium oxide; cinnamaldehyde; cinnamyl alcohol; platinum; selective hydrogenation; unsaturated alcohol synthesis; zirconium oxide; α,b-unsaturated aldehydes; cerium oxide; platinum; selective hydrogenation; cinnamyl alcohol; cinnamaldehyde; zirconium oxide; unsaturated alcohol synthesis; α,b-unsaturated aldehydes
• ISSN: 0959-9436
• DOI: 10.1016/j.mencom.2022.07.019

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Cerium–zirconium mixed oxides with different Ce/Zr ratio were prepared and used as supports for Pt-containing catalysts. The study of the catalysts in the cinnamaldehyde hydrogenation reaction has shown that cinnamaldehyde conversion and cinnamyl alcohol selectivity strongly depend on the CeO2 content in the support. The highest cinnamyl alcohol yield of 81% was obtained in 105 min at room temperature and atmospheric pressure over the 1%Pt/CeO2–ZrO2 catalyst with Ce : Zr atomic ratio equal to 4 : 1.