Mössbauer effect studies of Dy(Fe 0.4Co 0.6− x Ni x ) 2 intermetallics

• Published in: Journal of alloys and compounds Vol. 474; no. 1; pp. 42 - 47
• Main Authors: Stoch, P., Guzdek, P., Stoch, A., Pszczoła, J., Suwalski, J.
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier B.V 17-04-2009; Elsevier
• Subjects: [formula omitted] Mössbauer effect; Band structure; Condensed matter: electronic structure, electrical, magnetic, and optical properties; Curie temperature; Electron density of states and band structure of crystalline solids; Electron states; Exact sciences and technology; FLAPW calculations; Hyperfine interactions; Intermetallic compounds; Intermetallics; Magnetic hyperfine field; Magnetic moments; Magnetic resonances and relaxations in condensed matter, mössbauer effect; Mössbauer effect; other γ-ray spectroscopy; Physics; Band structure; Magnetic hyperfine field; 71.20.Lp; 75.50.Gg; Intermetallics; Magnetic moments; 76.30.Kg; Curie temperature; 61.10.Nz; Fe 57 Mössbauer effect; 72.15.Eb; FLAPW calculations; 71.20.Be; 71.20.Eh; Hyperfine interactions; Moessbauer effect; Intermetallic compounds; 57Fe Mössbauer effect; Iron alloys; Subband; Hyperfine magnetic field; Nickel alloys; Curie point; Band splitting; Magnetic transitions; APW calculations; Dysprosium alloys; Cobalt alloys; Transition element alloys
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2008.06.146

A consequence of Co/Ni substitution in the intermetallics Dy(Fe
0.4Co
0.6−
x
Ni
x
)
2 was tested in this paper.
Fe
57
Mössbauer effect measurements for the intermetallic system were carried out at 4.2
K and the determined hyperfine interaction parameters as functions of composition are reported. The magnetic hyperfine field as well as the Curie temperature is strongly reduced with a composition parameter
x. Band structure calculations using the full-potential linearized augmented plane waves (FLAPW) method were performed. Some properties of the 3d bands of the Fe, Co and Ni constituents are discussed. The 3d band splitting energies and the magnetic moments of transition metals reduce with
x. The experimentally determined magnetic hyperfine field correlates linearly with the calculated stoichiometrically weighted magnetic moment of 3d atoms and correlates linearly with the weighted splitting energy between 3d subbands. The Curie temperature changes nonlinearly with the squared magnetic hyperfine field or with the calculated squared weighted splitting energy between 3d subbands.