Silver@copper-polyaniline nanotubes: Synthesis, characterization and biosensor analytical study

• Published in: Results in Chemistry Vol. 9; p. 101614
• Main Authors: Saadh, Mohamed J., AL-Salman, H.N.K., Hussein, Hussein H., Mahmoud, Zaid H., Jasim, Hamza Hameed, Ward, Zahraa hassan, Alubiady, Mahmood Hasen shuhata, Al-Ani, Ahmed Muzahem, Jumaa, Sally Salih, Sayadi, Hamidreza, Kianfar, Ehsan
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01-07-2024
• Subjects: Bimetallic; Bimetallic nanoparticles; Biosensor; Cyclic voltammetry; DPV; Nanotube; Cyclic voltammetry; DPV; Bimetallic nanoparticles; Biosensor; Bimetallic; Nanotube
• ISSN: 2211-7156; 2211-7156
• DOI: 10.1016/j.rechem.2024.101614

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We introduce silver-copper nanoparticles incorporated into polyaniline (PANI) nanotubes using a straightforward and efficient reduction process. In this regard, PANI nanotubes with amine groups were fabricated through oxidation polymerization, followed by the attachment of Ag and Cu precursors to enable the synthesis of Ag-Cu bimetallic nanoparticles (NPs) on the pre-formed PANI nanotubes with the use of hydrazine as a reducing agent. The structural characterization of the synthesized NPs was investigated by UV–Vis spectrophotometer (UV–Vis), Dark-field emission, (EDX), X-ray diffraction (XRD) and field emission (FESEM), while the electrochemical properties were estimated by (CV) and differential pulse voltammetry (DPV). The findings indicated that the Ag-Cu NPs were present in the nanoscale range, well-dispersed, and attached to the surface of PANI nanotubes. Electrochemical investigations revealed that the Ag-Cu@PANI nanotube electrode demonstrated efficient electrooxidation of dopamine and hydroquinone without any interfering reactions, suggesting its potential use as an electrochemical biosensor for simultaneous detection of dopamine and hydroquinone. The proposed NPs-based biosensor was connected to concurrently identify dopamine and hydroquinone, illustrating moo distinguish Confinements of 0.46 µM for dopamine and 0.23 mM for hydroquinone, separately. Additionally, the manufactured sensor identified on a wide direct run the dopamine (5–25 µM), and hydroquinone (0.5–2.5 mM). Alongside these promising comes about, the Ag-Cu@PANI nanotube actualized great solidness and reproducibility, making it a favorable stage for electrochemical biosensing of dopamine and hydroquinone.