Optical and magnetic properties of PbO–Sb2O3–As2O3 glasses containing vanadium ions

PbO-Sb2O3-As2O3 glasses containing different concentrations of V2O5 (ranging from 0 to 0.5 mol%) were prepared. A number of studies, viz. optical absorption, IR spectra, thermoluminescence, ESR spectra and magnetic susceptibility on these glasses were carried out as a function of vanadium ion concen...

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Bibliographic Details
Published in:Materials letters Vol. 59; no. 5; pp. 539 - 545
Main Authors: Raghavaiah, B.V., Laxmi Kanth, C., Krishna Rao, D., Lakshman Rao, J., Veeraiah, N.
Format: Journal Article
Language:English
Published: 01-02-2005
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Summary:PbO-Sb2O3-As2O3 glasses containing different concentrations of V2O5 (ranging from 0 to 0.5 mol%) were prepared. A number of studies, viz. optical absorption, IR spectra, thermoluminescence, ESR spectra and magnetic susceptibility on these glasses were carried out as a function of vanadium ion concentration. An anomaly has been observed in all the properties of these glasses when V2O5 concentration is about 0.3 mol%. The results of these studies were analyzed in the light of different oxidation states of vanadium ions.
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ISSN:0167-577X
DOI:10.1016/j.matlet.2004.09.010