Influence of solid electrolyte particles size on ionic transport in model composite system (PVdF-HFP–Li1.3Al0.3Ti1.7(PO4)3)

• Published in: Ionics Vol. 19; no. 1; pp. 33 - 39
• Main Authors: Andreev, O. L., Druzhinin, K. V., Shevelin, P. Yu, Batalov, N. N.
• Format: Journal Article
• Language: English
• Published: Berlin/Heidelberg Springer-Verlag 2013
• Subjects: Chemistry; Chemistry and Materials Science; Condensed Matter Physics; Electrochemistry; Energy Storage; Optical and Electronic Materials; Original Paper; Renewable and Green Energy; Li-ion conductivity; Model system; Composite polymer electrolytes
• ISSN: 0947-7047; 1862-0760
• DOI: 10.1007/s11581-012-0706-z

The influence of filler particles size on lithium ion conductivity of composite polymer electrolytes was issued on model system vinylidenefluoride with hexafluoropropylene (PVdF-HFP)–Li
1.3
Al
0.3
Ti
1.7
(PO
4
)
3
. Model electrolyte objects with filler grains of different sizes were prepared using a modified solvent casting method from a mixture of PVdF-HFP solution in dimethylformamide and Li
1.3
Al
0.3
Ti
1.7
(PO
4
)
3
solid electrolyte particles. The percolation threshold was defined and the transport properties of composite polymer electrolytes at different volume concentrations of the solid electrolyte investigated. A significant decrease in conductivity compared to that of ceramic solid electrolytes was observed. The size of the filler particles was found to affect the structure and transport properties of the prepared composite polymer electrolytes. The conductivity of the composite polymer electrolyte at 100 °C was found to increase by two orders of magnitude with the tenfold increase of the size of the filler particles.