Formation and stabilization of monovalent nickel in the Ni(COD)2/BF3 · OEt2 catalytic system

Formation and stabilization of monovalent nickel in the Ni(COD)2/BF3 · OEt2 catalytic system

The catalytic system Ni(COD) 2 /BF 3 · OEt 2 was used to demonstrate the possibility of stabilizing Ni + ions in toluene solutions without traditional organoelement ligands.

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Bibliographic Details
Published in:Russian journal of coordination chemistry Vol. 34; no. 9; pp. 712 - 713
Main Authors: Saraev, V. V., Kraikivskii, P. B., Matveev, D. A., Petrovskii, S. K., Fedorov, S. V.
Format: Journal Article
Language:English
Published: Dordrecht SP MAIK Nauka/Interperiodica 01-09-2008
Subjects:
Chemistry
Chemistry and Materials Science
Inorganic Chemistry
Letters to the Editor
Physical Chemistry
Catalytic System
Toluene Solution
Phosphine Ligand
Lithium Hydride
Diphenylpicrylhydrazyl
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Description
Summary:The catalytic system Ni(COD) 2 /BF 3 · OEt 2 was used to demonstrate the possibility of stabilizing Ni + ions in toluene solutions without traditional organoelement ligands.
ISSN:1070-3284
1608-3318
DOI:10.1134/S1070328408090133