Optimizing the composition of barium-borate glasses for enhancing thermal neutron shielding efficiency: Monte Carlo simulation

• Published in: Radiation physics and chemistry (Oxford, England : 1993) Vol. 223; p. 111937
• Main Authors: Boontueng, P., Pencharee, S., Mutuwong, C., Kaewkhao, J., Thongjerm, P., Wonglee, S., Kothan, S., Intachai, N., Kobdaj, C.
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01-10-2024
• Subjects: Barium-borate glasses; Gamma-ray shielding; Neutron shielding; Thermal neutron; Barium-borate glasses; Gamma-ray shielding; Neutron shielding; Thermal neutron
• ISSN: 0969-806X; 1879-0895
• DOI: 10.1016/j.radphyschem.2024.111937

A transparent window with thermal neutron shielding properties was an important part of the stations of the nuclear reactors and the particle accelerators. The borate glass with a high neutron cross section was a candidate as a glass network for the neutron shielding window. In order to slow down thermal neutrons, they were trapped by boron and subsequently emitted secondary radiation, such as alpha particles and gamma-ray radiation. This work was to optimize the content between a ratio of borate with a high cross-section neutron interaction and barium for shielding alpha and gamma ray. The barium-borate glasses were successfully synthesized using the melting technique in the atmosphere. Measurements of mechanical and optical glass properties were presented. The measured results showed that an increase in barium oxide content in the glass ratio enhanced the glass density and the transmittance at a visible wavelength. In the calculation of radiation shielding properties, FLUKA code based on Monte Carlo Simulation was demonstrated. The calculated results revealed that an increase in the barium oxide content in the glass composition reduced the thermal neutron shielding properties of the glass samples. In contrast, the glass with barium contents enhanced the photon-shielding efficiency, as indicated by the mass attenuation coefficient and half-value layer. Not only the ratio of the barium and borate contents affected the shielding properties, but the increased glass thickness also enhanced the shielding properties. Thus, the utilization of cooperative borate glasses and barium with appropriate thickness could potentially serve as a viable option for simultaneously protecting against thermal neutrons and photons. The barium-borate glasses with our composition might be used as a window in a thermal neutron station as well as for photon radiation.
•The glass composition with BaO–AlF3–Na2O–B2O3 were prepared.•The thermal neutron and gamma shielding properties were calculated using the Flair graphical interface for FLUKA code.•A 0.48 MeV gamma ray was detected due to the thermal neutron and a boron reaction.•The glass with a higher BaO content reduced neutron shielding properties but enhanced the gamma shielding properties.