Dahlia ball shape bimetallic phosphide-tungsten phosphide composite for anion-exchange membrane water electrolysis

• Published in: International journal of hydrogen energy Vol. 90; pp. 1378 - 1389
• Main Authors: Balu, Ranjith, Devendrapandi, Gautham, Gnanasekaran, Lalitha, Karthika, P.C., Abd-Elkader, Omar H., Kim, Woo Kyoung, Minnam Reddy, Vasudeva Reddy, Kapoor, Monit, Singh, Suresh, Lavanya, Mahimaluru
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 11-11-2024
• Subjects: Bimetallic phosphide; Electrocatalyst; Electrochemical water splitting; Overall water splitting; Electrochemical water splitting; Electrocatalyst; Overall water splitting; Bimetallic phosphide
• ISSN: 0360-3199
• DOI: 10.1016/j.ijhydene.2024.10.043

Revolutionizing Water Splitting: Introducing a Breakthrough Single Heterostructure Catalyst for Highly Efficient Hydrogen and Oxygen Evolution Reactions. In this study, we present an innovative method for water splitting that introduces a remarkable single heterostructure catalyst capable of efficiently catalyzing both the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). Our research utilizes a highly effective hydrothermal synthesis technique to create a unique nanosphere composed of iron cobalt phosphide and tungsten phosphide (FCPWP). This FCPWP nanosphere exhibits finely tuned electronic structures and incorporates multiple active sites, resulting in significantly reduced overpotentials. When operating at current densities of 50 and 100 mA cm−2, the HER overpotentials are as low as 220 mV and 280 mV, respectively, while the OER overpotentials are only 270 mV and 350 mV. By employing the FCPWP nanosphere in a two-electrode electrolyzer configuration, we achieve exceptional results with minimal power requirements. At an operating current density of 10 mA cm−2, the electrolyzer functions at an impressively low voltage of 1.44 V, and at 1.85 V, it attains a high current density of 425 mA cm−2, showcasing an outstanding cell efficiency of 71.63% in an anion exchange membrane electrolyzer. These experimental findings are further supported by computational study. The FCPWP nanosphere emerges as an extraordinary electrocatalyst with dual-functionality for water splitting, offering great promise in the efficient production of hydrogen through electrochemical means. Our research not only introduces a fresh perspective but also paves the way for significant advancements in renewable energy technologies.
•A novel, efficient, and stable bifunctional catalyst was created and tested.•A cell efficiency of 71.63% was attained using an ion exchange membrane electrolyzer.•The electrolyzer operated at a voltage of 1.85 V and a current density of 425A cm−2.•The necessary cell potential for a current density of 10 mAcm−2 was determined to be 1.44 V.