Effect of the oil content on green hydrogen production from produced water using carbon quantum dots as a disruptive nanolectrolyte

• Published in: International journal of hydrogen energy Vol. 76; pp. 353 - 362
• Main Authors: Ríos, Ever Herrera, Guzmán, Juan D., Ribadeneira, Rafael, Bailón-García, Esther, Acevedo, Elizabeth Rodríguez, Vélez, Fredy, Franco, Camilo A., Riazi, Masoud, Cortes, Farid B.
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 26-07-2024
• Subjects: CQDs; Crude oil; Electrolysis; Graphite; Hydrogen; Produced water; CQDs; Electrolysis; Produced water; Crude oil; Hydrogen; Graphite
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2024.05.458

Considering that high-purity fresh water is employed in the green production of hydrogen via commercial water electrolyzers and that over 80% of the global population faces significant water safety risks, it is essential to explore alternative water sources. One such alternative is the use of produced water from oil extraction processes. Hence, the main objective of this study is to evaluate the effect of the oil content of oilfield production water on the production of green hydrogen by electrolysis in the presence of carbon quantum dots (CQDs). For this purpose, various electrochemical techniques, such as linear sweep voltammetry (LSV), cyclic voltammetry (CV), and potentiometry, were used to identify the effect of crude oil during hydrogen production. Thermogravimetric analysis (TGA), mass spectrometry (MS), and Fourier-transform infrared spectroscopy (FTIR) were employed to discern the adsorption of crude oil onto the electrodes, quantify the gas fractions generated during the process and identify the functional groups present after the procedure, respectively. Also, optical microscopy was employed to follow the droplet size in the emulsion. The results show that using CQDs affects the Faradaic efficiency, which increases from 77% to 83% with the incorporation of CQDs. In the presence of CQDs, the effects generated by the presence of the oil are inhibited at low oil concentrations.
On the contrary, hydrogen production increases by 10.0% (0.1 mL/min) with a faradaic efficiency of 83% and a half-cell efficiency of 41%, compared to the record obtained with the maximum concentration of emulsified crude oil (400 mg/L). The mean size of the initial emulsion droplets was 3.4 μm. At the end of the test, there was evidence of complete breakage of the emulsion due to the effect of the applied electric field. No evidence of adsorption of crude oil on graphite electrodes during electrolysis is observed based on the tests. It has been shown that green hydrogen production from crude oil production water is feasible due to the proposed disruptive electrolytes in the produced water, which inhibit the effect of oil content in the O/W emulsion. This allows the implementation of a new green energy production initiative aligned with the global goal of achieving net zero emissions (NZE) by 2050. The current investigation presents a prospective alternative for harnessing the 18 kW electrical energy potential employed within emulsion-breaking processes within a Colombian field for treatment of around 1000 bpd. This alternative offers a theoretical potential for hydrogen production, approximating 7.36 kW, thus representing a promising opportunity for practical field deployment.
•CQDs in electrolysis enhance green hydrogen production efficiency from oilfield-produced water due to their conductive properties.•CQDs significantly increases Faradaic efficiency, inhibiting crude oil's negative effects on hydrogen generation.•Optimized electrolysis with CQDs result in 10% higher hydrogen production at high concentrations of emulsified crude oil.•CQDs mitigate crude oil's negative effects on the system, such as reduced conductivity and electrode degradation.•Gas analysis demonstrates the feasibility of converting oilfield production water into a valuable resource for green energy.