Dumbbell Impurities in 2D Crystals of Repulsive Colloidal Spheres Trap Dislocations

Impurity-induced defects play a crucial role for the properties of crystals, but little is known about impurities with anisotropic shape. Here, we study how colloidal dumbbells distort and interact with a hexagonal crystal of charged colloidal spheres at a fluid interface. We find that subtle differ...

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Bibliographic Details
Published in:Physical review letters Vol. 133; no. 15; p. 158202
Main Authors: Meester, Vera, van der Wel, Casper, Verweij, Ruben W, Biondaro, Giovanni, Kraft, Daniela J
Format: Journal Article
Language:English
Published: United States 11-10-2024
Online Access:Get full text
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Summary:Impurity-induced defects play a crucial role for the properties of crystals, but little is known about impurities with anisotropic shape. Here, we study how colloidal dumbbells distort and interact with a hexagonal crystal of charged colloidal spheres at a fluid interface. We find that subtle differences in the dumbbell length determine whether it induces a local distortion of the lattice or traps a dislocation, and determine how the dumbbell moves inside the repulsive hexagonal lattice. Our results provide new routes toward controlling material properties and understanding fundamental questions in phase transitions through particle-bound dislocations.
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ISSN:0031-9007
1079-7114
1079-7114
DOI:10.1103/PhysRevLett.133.158202