Toward efficient functionalization of polystyrene backbone through ketene chemistry: Synthesis, characterization, and DFT study

• Published in: Polymers for advanced technologies Vol. 34; no. 2; pp. 587 - 596
• Main Authors: Heydari, Abolfazl, Hosseini, Maryam, Darroudi, Mahdieh, Behzadi, Masoumeh, Hronský, Viktor, Sučik, Gabriel, Rouh, Hossein, Sheibani, Hassan
• Format: Journal Article
• Language: English
• Published: Chichester, UK John Wiley & Sons, Ltd 01-02-2023; Wiley Subscription Services, Inc
• Subjects: Acids; Chemical analysis; Chemical synthesis; Density functional theory; Differential thermogravimetric analysis; Energy value; Gibbs free energy; Heat treatment; ketene; Ketenes; mechanism; Meldrum's acid; NMR; Nuclear magnetic resonance; polystyrene; Polystyrene resins; Reagents; Styrenes; Substitution reactions; Syndiotacticity; Thermogravimetric analysis
• ISSN: 1042-7147; 1099-1581
• DOI: 10.1002/pat.5910

In this study, polystyrene was functionalized with Meldrum's acid toward the introduction of the ketenes (CCO) system to its backbone for producing a dramatically reactive intermediate. Meldrum's acid, as a ketene source, was reacted by poly(styrene‐co‐p‐chloromethyl styrene) through a simple nucleophilic reaction to synthesize poly(styrene‐co‐styryl Meldrum's acid). Then, the pendant Meldrum's acid under thermal treatment converted to ketene intermediate resulting in highly reactive polystyrenes derivatives, which rapidly reacted by nucleophilic reagents to afford ultimate organic building blocks. The polystyrene derivatives were characterized using elemental analysis, FT‐IR, high‐resolution solid‐state NMR, thermogravimetric analysis (TGA), and differential thermogravimetric analysis (DTG). To clarify the evolutionary mechanisms of polystyrene products, density functional theory (DFT) method B3LYP with the 6–311++G(2d,p) basis set was used. We studied the preparation of polystyrene model compounds through Meldrum's acid thermolysis and nucleophilic substitution. The kinetic and thermodynamic parameters in all reactions and the structural and electronic properties of all molecules were calculated. These data exhibited that based on Gibbs Free energy values, the structure of syndiotactic polystyrene is more stable than that of isotactic polystyrene. Furthermore, it was found that the presence of an electron donor or acceptor substituent on the polystyrene structure affects the electronic bandgap.