Chapter 5 Hetarylazomethine Metal Complexes

Chapter 5 Hetarylazomethine Metal Complexes

This chapter discusses hetarylazomethine metal complexe. This reactivity pattern is illustrated by the interaction of the aforementioned metal sources with cyclic and acyclic azomethines. Complexes of acyclic azomethines involve chelates of Schiff bases, b-aminovinylketones, and b-aminovinylimines c...

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Published in:Advances in Heterocyclic Chemistry Vol. 97; pp. 291 - 392
Main Authors: Garnovskii, Alexander D., Sadimenko, Alexander P., Vasilchenko, Igor S., Garnovskii, Dmitry A., Sennikova, Evgeniya V., Minkin, Vladimir I.
Format: Book Chapter
Language:English
Published: Elsevier Science & Technology 2009
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Abstract This chapter discusses hetarylazomethine metal complexe. This reactivity pattern is illustrated by the interaction of the aforementioned metal sources with cyclic and acyclic azomethines. Complexes of acyclic azomethines involve chelates of Schiff bases, b-aminovinylketones, and b-aminovinylimines containing heterocyclic moieties. In the multinuclear coordination compounds under this chapter, the heterocyclic frameworks play the role of the aldehyde, amine, and/or adduct-forming constituents. In the oligonuclear structures, heterocycles may also play the role of the intermetal bridges. The data collected in this chapter are generalized and systematized with emphasis on the specified functions in the structure of azomethine ligands and heterocyclic frameworks.
AbstractList This chapter discusses hetarylazomethine metal complexe. This reactivity pattern is illustrated by the interaction of the aforementioned metal sources with cyclic and acyclic azomethines. Complexes of acyclic azomethines involve chelates of Schiff bases, b-aminovinylketones, and b-aminovinylimines containing heterocyclic moieties. In the multinuclear coordination compounds under this chapter, the heterocyclic frameworks play the role of the aldehyde, amine, and/or adduct-forming constituents. In the oligonuclear structures, heterocycles may also play the role of the intermetal bridges. The data collected in this chapter are generalized and systematized with emphasis on the specified functions in the structure of azomethine ligands and heterocyclic frameworks.
Author Minkin, Vladimir I.
Sennikova, Evgeniya V.
Sadimenko, Alexander P.
Garnovskii, Alexander D.
Vasilchenko, Igor S.
Garnovskii, Dmitry A.
Author_xml – sequence: 1
  givenname: Alexander D.
  surname: Garnovskii
  fullname: Garnovskii, Alexander D.
  organization: Institute of Physical and Organic Chemistry of the Southern Federal University, Stachka Avenue, 194/2, Rostov on Don 344090, Russia
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  givenname: Alexander P.
  surname: Sadimenko
  fullname: Sadimenko, Alexander P.
  organization: Department of Chemistry, University of Fort Hare, Alice 5700, Republic of South Africa
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  givenname: Igor S.
  surname: Vasilchenko
  fullname: Vasilchenko, Igor S.
  organization: Institute of Physical and Organic Chemistry of the Southern Federal University, Stachka Avenue, 194/2, Rostov on Don 344090, Russia
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  givenname: Dmitry A.
  surname: Garnovskii
  fullname: Garnovskii, Dmitry A.
  organization: Institute of Physical and Organic Chemistry of the Southern Federal University, Stachka Avenue, 194/2, Rostov on Don 344090, Russia
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  givenname: Evgeniya V.
  surname: Sennikova
  fullname: Sennikova, Evgeniya V.
  organization: Institute of Physical and Organic Chemistry of the Southern Federal University, Stachka Avenue, 194/2, Rostov on Don 344090, Russia
– sequence: 6
  givenname: Vladimir I.
  surname: Minkin
  fullname: Minkin, Vladimir I.
  organization: Institute of Physical and Organic Chemistry of the Southern Federal University, Stachka Avenue, 194/2, Rostov on Don 344090, Russia
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Snippet This chapter discusses hetarylazomethine metal complexe. This reactivity pattern is illustrated by the interaction of the aforementioned metal sources with...
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Title Chapter 5 Hetarylazomethine Metal Complexes
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