Chapter 5 Hetarylazomethine Metal Complexes

Chapter 5 Hetarylazomethine Metal Complexes

This chapter discusses hetarylazomethine metal complexe. This reactivity pattern is illustrated by the interaction of the aforementioned metal sources with cyclic and acyclic azomethines. Complexes of acyclic azomethines involve chelates of Schiff bases, b-aminovinylketones, and b-aminovinylimines c...

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Bibliographic Details
Published in:Advances in Heterocyclic Chemistry Vol. 97; pp. 291 - 392
Main Authors: Garnovskii, Alexander D., Sadimenko, Alexander P., Vasilchenko, Igor S., Garnovskii, Dmitry A., Sennikova, Evgeniya V., Minkin, Vladimir I.
Format: Book Chapter
Language:English
Published: Elsevier Science & Technology 2009
Online Access:Get full text
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Summary:This chapter discusses hetarylazomethine metal complexe. This reactivity pattern is illustrated by the interaction of the aforementioned metal sources with cyclic and acyclic azomethines. Complexes of acyclic azomethines involve chelates of Schiff bases, b-aminovinylketones, and b-aminovinylimines containing heterocyclic moieties. In the multinuclear coordination compounds under this chapter, the heterocyclic frameworks play the role of the aldehyde, amine, and/or adduct-forming constituents. In the oligonuclear structures, heterocycles may also play the role of the intermetal bridges. The data collected in this chapter are generalized and systematized with emphasis on the specified functions in the structure of azomethine ligands and heterocyclic frameworks.
ISBN:9780123747334
0123747333
ISSN:0065-2725
1557-8429
DOI:10.1016/S0065-2725(08)00205-5