The impacts of CO2 on sandstone reservoirs in different fluid environments: insights from mantle-derived CO2 gas reservoirs in Dongying Sag, Bohai Bay Basin, China

• Published in: Frontiers in earth science (Lausanne) Vol. 12
• Main Authors: Wang, Maoyun, Zeng, Jianhui, Li, Chuanming, Qiao, Juncheng, Wei, Wenfei, Zhang, Huanle, Cui, Huwang
• Format: Journal Article
• Language: English
• Published: Frontiers Media S.A 07-11-2024
• Subjects: CO2-water-rock interaction; diagenesis; Dongying Sag; fluid environment; mantle-derived CO2
• ISSN: 2296-6463; 2296-6463
• DOI: 10.3389/feart.2024.1436573

Introduction Mantle-derived CO 2 , as an important component of hydrothermal fluids, is widely distributed in petroliferous basins. While previous experimental studies have suggested that CO 2 can improve sandstone reservoir quality through mineral dissolution in open fluid setting, they have overlooked its nagetive effects to sandstone reservoir quality by carbonate cementation. Additionally, the roles of various fluid environments in CO 2 -reservoir interactions have not been studied in detail. Methods To systematically investigate the influences of CO 2 on sandstone reservoirs, we examine a typical mantle-derived CO 2 gas reservoir, Bohai Bay Basin, China. This study employs integrated methods, including electron microscopy, scanning electron microscopy, X-ray diffraction, stable C- and O-isotope analysis, and physical property data. The aim is to investigate the evidence and mechanisms by which mantle-derived CO 2 impacts sandstone reservoirs, particularly focusing on its effects in open and closed fluid environments. Results and Discussion Our findings reveal that dawsonite and ankerite are prevalent within the mantle-derived CO 2 gas reservoir, while isotopic analysis of carbonate cements indicates values (δ 13 C: −9.0‰ to −1.6‰; δ 18 O: −21.7‰ to −12.7‰) consistent with mantle-derived CO 2 and hydrothermal fluids. These pieces of evidence indicate that CO 2 -rich hydrothermal fluids participate in water-rock interactions, thereby significantly influencing the diagenesis of reservoirs. Further, we notice that CO 2 reservoirs adjacent to faults exhibit an open fluid environment, characterized by superior porosity and permeability, more quartz, but fewer feldspar, carbonate, and clay minerals compared to those in closed fluid environments. Notably, kaolinite predominates in open fluid environments, while illite/smectite (I/S) is more common in closed settings. The dual roles of mantle-derived CO 2 are highlighted in our analysis: while it enhances reservoir storage and permeability through mineral dissolution, the carbonate cement generated by CO 2 -water-rock interaction can also adversely affect reservoir quality. In open fluid environments, CO 2 facilitates the dissolution of feldspar and carbonate minerals, promoting the timely removal of dissolution by-products (clay mineral) and inhibiting carbonate cementation, thereby improving reservoir properties. Conversely, in closed fluid environments, decreasing CO 2 concentrations with depth leads to diminishing dissolution effects and increased carbonate cementation, resulting in reduced reservoir porosity and permeability. Overall, the significance of this study is to correct the deviation in the impacts of CO 2 on sandstone reservoirs at laboratory setting through case study of typical mantle-source CO 2 gas reservoir. This work can be applied to the studies of reservoir homogeneity and sweet spots in regions with hydrothermal and mantle-derived CO 2 activities. However, due to the limitation of CO 2 content range (about 15%–70%) in the study case, we are unable to investigate the effects of low-concentration CO 2 on sandstone reservoirs, which may affect the generalizability of this work. Besides, the formation temperature and pressure, and salinity of formation water, should be considered when dealing with other cases.