Polarisation labelling spectroscopy of the 51Π state in KCs molecule

[Display omitted] •The 51Π←X1Σ+ band system of KCs observed by polarisation labelling spectroscopy.•The pointwise potential curve of the 51Π state constructed from experimental data.•The result compared with the prediction of theoretical calculations. We present an experimental investigation of the...

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Bibliographic Details
Published in:Chemical physics letters Vol. 638; pp. 78 - 81
Main Author: Szczepkowski, Jacek
Format: Journal Article
Language:English
Published: Elsevier B.V 01-10-2015
Online Access:Get full text
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Summary:[Display omitted] •The 51Π←X1Σ+ band system of KCs observed by polarisation labelling spectroscopy.•The pointwise potential curve of the 51Π state constructed from experimental data.•The result compared with the prediction of theoretical calculations. We present an experimental investigation of the 51Π state of KCs using the polarisation labelling spectroscopy technique. A pointwise potential energy curve was constructed from 1146 energy levels with use of the inverted perturbation approach.
ISSN:0009-2614
1873-4448
DOI:10.1016/j.cplett.2015.08.037