Efficient tunable visible and near-infrared emission in Sb3+/Sm3+-codoped Cs2NaLuCl6 for near-infrared light-emitting diode, triple-mode fluorescence anti-counterfeiting and information encryption

• Published in: Chinese chemical letters Vol. 35; no. 11; p. 109462
• Main Authors: Peng, Hui, Wang, Xiao, Huang, Weiguo, Yu, Shuiyue, Kong, Linghang, Wei, Qilin, Zhao, Jialong, Zou, Bingsuo
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01-11-2024
• Subjects: Energy transfer; Multifunctional applications; Near-infrared emission; Rare earth-based double perovskites; Self-trapped exciton; Rare earth-based double perovskites; Multifunctional applications; Energy transfer; Near-infrared emission; Self-trapped exciton
• ISSN: 1001-8417
• DOI: 10.1016/j.cclet.2023.109462

Rare earth ions (RE3+)-doped double perovskites have attracted tremendous attention for its fascinating optical properties. Nevertheless, RE3+ generally exhibits poor photoluminescence quantum yield (PLQY) for their parity-forbidden 4f-4f transition and the low doping concentration. Herein, we reported Sb3+/Sm3+-codoped rare earth-based double perovskite Cs2NaLuCl6 that enables efficient visible and near-infrared (NIR) emission, which stems from self-trapped exciton (STE) and Sm3+, respectively. Benefit from up to 72.89% energy transfer efficiency from STE to Sm3+ and high doping concentrations due to similar ionic activity between Sm3+ and Lu3+, thus eruptive PLQY of 74.58% in the visible light region and 23.12% in the NIR light region can be obtained. Moreover, Sb3+/Sm3+-codoped Cs2NaLuCl6 exhibits tunable emission characteristic in the visible light region under different excitation wavelengths, which can change from blue emission (254 nm excitation) to white emission (365 nm excitation). More particularly, only the NIR emission can be captured by the NIR camera when a 700 nm cutoff filter is added. The excellent stability and unique optical properties of Sb3+/Sm3+-codoped Cs2NaLuCl6 enable us to demonstrate its applications in NIR light-emitting diode, triple-mode fluorescence anti-counterfeiting and information encryption. These findings provide new inspiration for the application of rare earth-based double perovskite in optoelectronic devices.
We report Sb3+/Sm3+-codoped double perovskite Cs2NaLuCl6, which shows efficient tunable visible and near-infrared emission. Parallelly, we further demonstrate the applications of Sb3+/Sm3+-codoped Cs2NaLuCl6 in night vision, biomedical imaging, triple-mode fluorescence anti-counterfeiting and information encryption. [Display omitted]